SYNTHESIS, CHARACTERIZATION, AND PROPERTIES OF REACTIVE LIQUID RUBBERS BASED ON BUTADIENE ACRYLONITRILE COPOLYMERS

被引：27

作者：

CHEN, D

PASCAULT, JP

BERTSCH, RJ

DRAKE, RS

SIEBERT, AR

机构：

[1] INST NATL SCI APPL, MAT MACROMOLEC LAB,CNRS,URA 507,20 AVE A EINSTEIN, F-69621 VILLEURBANNE, FRANCE

[2] BF GOODRICH CO, CTR RES & DEV, DIV SPECIALTY POLYMERS & CHEM, BRECKSVILLE, OH 44141 USA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1994年 / 51卷 / 11期

关键词：

D O I：

10.1002/app.1994.070511112

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Reactive liquid polymers (RLP), carboxyl-terminated butadiene-acrylonitrile copolymers (CTBN), epoxy-terminated butadiene-acrylonitrile copolymers (ETBN), amine-terminated butadiene-acrylonitrile copolymers (ATBN) of different molecular weights (from 2200 to 6500 g/mol), and a nonfunctional butadiene-acrylonitrile copolymer were synthesized and characterized. Selection of end groups of RLPs and the synthesis were discussed. Phase behaviors of CTBN, ETBN, and NFBN in the RLP/DGEBA system were investigated regarding to the molecular weight, molecular weight distribution, chain composition, and end groups with a light transmission method. These experimentally determined phase behaviors will be related to those of the RLPs in the systems to be modified. The effect of molecular weight of RLP on the viscosity was also studied. (C) 1994 John Wiley & Sons, Inc.

引用

页码：1959 / 1970

页数：12

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