THE SYNTHESIS AND COMPLETE H-1 NMR AND C-13 NMR SPECTRAL ASSIGNMENT OF 2,2,4,4,6,6-HEXANITROADAMANTANE AND ITS PRECURSOR NITROKETONES BY 2D NMR-SPECTROSCOPY

被引：13

作者：

DAVE, PR

BRACUTI, A

AXENROD, T

LIANG, BM

机构：

[1] USA,CTR DEV & ENGN,PICATINNY ARSENAL,NJ 07806

[2] CUNY CITY COLL,DEPT CHEM,NEW YORK,NY 10031

来源：

TETRAHEDRON | 1992年 / 48卷 / 28期

关键词：

D O I：

10.1016/S0040-4020(01)90175-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of 2,2,4,4,6,6-hexanitroadamantane from the precursors, 4,4,6,6-tetranitroadamantan-2-one and 4,4-dinitroadamantane-2,6-dione is reported. The complete H-1 and C-13 NMR assignment of these compounds by 2D C-13-H-1 shift correlated spectra, H-1-H-1 COSY spectra and H-1-H-1 NOESY spectra is described.

引用

页码：5839 / 5846

页数：8

共 10 条

[1]

ALSTER J, 1990, CHEM PHYSICS ENERGET, P641

[2] SYNTHESIS OF POLYNITROADAMANTANES - OXIDATIONS OF OXIMINOADAMANTANES [J].