CLUSTER CHEMISTRY .68. SUBSTITUTION OF CO BY P(OET)3 IN RU5(MU-5-C2PPH2)(MU-PPH2)(CO)13 - X-RAY STRUCTURES OF 2 ISOMERS OF RU5(MU-5-C2PPH2)(MU-PPH2)(CO)12(P(OET)3) AND OF RU5(MU-5-C2PPH2)(MU-PPH2)(CO)11(P(OET)3)2

被引：6

作者：

BRUCE, MI

LIDDELL, MJ

TIEKINK, ERT

NICHOLSON, BK

SKELTON, BW

WHITE, AH

机构：

[1] UNIV WAIKATO,SCH CHEM,HAMILTON,NEW ZEALAND

[2] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80007-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Ru5(mu-5-C2PPh2)(mu-PPh2)(CO)13 (1) with P(OEt)3 occur preferentially at basal (thermal) or wing-tip Ru atoms (Me3NO-induced); disubstitution gave a complex in which both phosphite ligands were on wing-tip Ru atoms, as did the reaction between 1 and PMe2Ph. The X-ray structures of two isomers of the mono-substituted complex, containing P(OEt)3 on wing-tip or basal Ru atoms, and of the disubstituted P(OEt)3 complex were determined.

引用

页码：211 / 229

页数：19

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