ALKALI-HALIDE CLUSTER IONS PRODUCED BY LASER VAPORIZATION OF SOLIDS

被引:104
作者
TWU, YJ
CONOVER, CWS
YANG, YA
BLOOMFIELD, LA
机构
[1] Department of Physics, University of Virginia, Charlottesville
来源
PHYSICAL REVIEW B | 1990年 / 42卷 / 08期
关键词
D O I
10.1103/PhysRevB.42.5306
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The mass spectra of alkali-halide cluster ions M(MX)n+ and X(MX)n-, produced by laser vaporization of a solid sample, were measured by tilted-plate time-of-flight mass spectrometry. The measured abundances of sodium chloride clusters (n=1200), sodium iodide clusters (n=1125), cesium chloride clusters (n=1125), and cesium iodide clusters (n=1100) confirm that surface terraces are the most stable additions to a cuboid base lattice. Also, the spectra show that the relative stabilities of certain cluster ions are dependent on the ionic radii of the constituent atoms. © 1990 The American Physical Society.
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页码:5306 / 5316
页数:11
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