SYNTHESIS OF STERICALLY HINDERED TELLUROPHENOLS AND THE STRUCTURE OF [CD(MU-TEC6H2ME3)2]-INFINITY

被引:70
作者
BOCHMANN, M [1 ]
COLEMAN, AP [1 ]
WEBB, KJ [1 ]
HURSTHOUSE, MB [1 ]
MAZID, M [1 ]
机构
[1] QUEEN MARY & WESTFIELD COLL, DEPT CHEM, LONDON E1 4NS, ENGLAND
关键词
D O I
10.1002/anie.199109731
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Useful starting compounds for the synthesis of metal complexes are provided by the thermally sensitive and photosensitive tellurophenols 1 (R = Me, iPr, tBu). For instance, the methyl‐substituted compound 1 reacts with [Cd{N(SiMe3)2}2] to give [Cd(TeC6H2Me3)2]∞, whose linear one‐dimensional chain structure is due to the spatial bulk of the mesityl groups. (Figure Presented.) Copyright © 1991 by VCH Verlagsgesellschaft mbH, Germany
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页码:973 / 975
页数:3
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