RATE CORRELATION OF PHOTOINDUCED ELECTRON-TRANSFER TO C-70

被引：37

作者：

OSAKI, T

TAI, Y

TAZAWA, M

TANEMURA, S

INUKAI, K

ISHIGURO, K

SAWAKI, Y

SAITO, Y

SHINOHARA, H

NAGASHIMA, H

机构：

[1] NAGOYA UNIV, FAC ENGN, DEPT APPL CHEM, CHIKUSA KU, NAGOYA 46401, JAPAN

[2] TOYOHASHI UNIV TECHNOL, SCH MAT SCI, TOYOHASHI 441, JAPAN

[3] MIE UNIV, FAC ENGN, DEPT ELECT ENGN, TSU, MIE 514, JAPAN

[4] MIE UNIV, FAC ENGN, DEPT CHEM MAT, TSU, MIE 514, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 05期

关键词：

D O I：

10.1246/cl.1993.789

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quenching rate constants (k(q)) of triplet C70 by electron donors have been measured by laser flash spectroscopy in benzonitrile and in acetonitrile-benzene (1:4). A plot of k(q) values versus free energy change for the electron transfer to 3C70 gives a fairly good correlation with rate constants calculated from the Rehm-Weller equation if corrected the diffusion-controlled rates in solvents used.

引用

收藏

页码：789 / 792

页数：4

相关论文

共 19 条

[1] 2 DIFFERENT FULLERENES HAVE THE SAME CYCLIC VOLTAMMETRY [J].

ALLEMAND, PM ;

KOCH, A ;

WUDL, F ;

RUBIN, Y ;

DIEDERICH, F ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) :1050-1051

[2] PHOTOPHYSICAL PROPERTIES OF C60 [J].

ARBOGAST, JW ;

DARMANYAN, AP ;

FOOTE, CS ;

RUBIN, Y ;

DIEDERICH, FN ;

ALVAREZ, MM ;

ANZ, SJ ;

WHETTEN, RL .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (01) :11-12

[3] ELECTRON-TRANSFER TO TRIPLET C-60 [J].

ARBOGAST, JW ;

FOOTE, CS ;

KAO, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (06) :2277-2279

[4] PHOTOPHYSICAL PROPERTIES OF C-70 [J].

ARBOGAST, JW ;

FOOTE, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8886-8889

[5]

Chanon M., 1988, PHOTOINDUCED ELECTRO

[6] ELECTROCHEMISTRY OF SOME SUBSTITUTED PYRROLES [J].

DIAZ, AF ;

MARTINEZ, A ;

KANAZAWA, KK .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1981, 130 (1-3) :181-187

[7] TRANSIENT ABSORPTION, LIFETIME AND RELAXATION OF C60 IN THE TRIPLET-STATE [J].

KAJII, Y ;

NAKAGAWA, T ;

SUZUKI, S ;

ACHIBA, Y ;

OBI, K ;

SHIBUYA, K .

CHEMICAL PHYSICS LETTERS, 1991, 181 (2-3) :100-104

[8]

KUZMIN BA, 1987, IZV AKAD NAUK SSSR K, V612

[9] CHEMISTRY OF SINGLET OXYGEN .37. ONE-ELECTRON OXIDATION OF TETRAMETHYLPHENYLENEDIAMINE BY SINGLET OXYGEN [J].

MANRING, LE ;

FOOTE, CS .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (08) :1257-1259

[10] PRODUCTION OF C-60 RADICAL CATION BY PHOTOSENSITIZED ELECTRON-TRANSFER [J].

NONELL, S ;

ARBOGAST, JW ;

FOOTE, CS .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (11) :4169-4170