TRANSITION-METAL CARBENE COMPLEXES .114. PENTACARBONYL(DIETHYLAMINO(TRIPHENYLSTANNYL)CARBENE)CHROMIUM(O)

被引：41

作者：

FISCHER, EO

PARDY, RBA

SCHUBERT, U

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 181卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)85735-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pentacarbonyl[diethylamino(triphenylstannyl)carbene]chromium(0) has been prepared by the reaction of the cationic carbyne complex [(CO)5Cr≡CNEt2]BF4 with Ph3SnK, and it crystallizes with dichloromethane in the monoclinic space group P21/c (Z = 4) with a 1478(5), b 1208(4), c 1855(6) pm and β 111.4(2)°. Cr--Ccarbene 211.0(14) pm, Sn--Ccarbene 223.9(14) pm. © 1979.

引用

页码：37 / 45

页数：9

共 37 条

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