EPOXIDATION OF OLEFINS CATALYZED BY POLYMER-SUPPORTED METAL BETA-KETOESTERATO COMPLEXES OF IRON(III), NICKEL(II) AND COBALT(II)

被引：24

作者：

DELLANNA, MM ^{[1
]}

MASTRORILLI, P ^{[1
]}

NOBILE, CF ^{[1
]}

SURANNA, GP ^{[1
]}

机构：

[1] POLITECN BARI,IST CHIM,CNR,CTR STUDI METODOL INNOVAT SINTESI ORGAN,I-70126 BARI,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 103卷 / 01期

关键词：

EPOXIDATION; COBALT; IRON; KETOESTERATE; NICKEL; POLYMER-SUPPORTED CATALYSIS;

D O I：

10.1016/1381-1169(95)00094-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The epoxidation of linear and cyclic olefins was catalysed by iron(III), nickel(II) and cobalt(II) centres immobilized on insoluble polymers. The latter were obtained by reaction of the polymerizable complexes of Fe(III), Ni(II) and Co(II) with 2-(acetoacetoxy)ethyl methacrylate with acrylamides.

引用

页码：17 / 22

页数：6

共 22 条

[1] USE OF MOLECULAR-OXYGEN IN THE BAEYER-VILLIGER OXIDATION THE INFLUENCE OF METAL-CATALYSTS [J].

BOLM, C ;

SCHLINGLOFF, G ;

WEICKHARDT, K .

TETRAHEDRON LETTERS, 1993, 34 (21) :3405-3408

[2] EPOXIDATION OF OLEFINS BY MOLECULAR-OXYGEN WITH CLAY-IMPREGNATED NICKEL-CATALYSTS [J].

BOUHLEL, E ;

LASZLO, P ;

LEVART, M ;

MONTAUFIER, MT ;

SINGH, GP .

TETRAHEDRON LETTERS, 1993, 34 (07) :1123-1126

[3]

CORAIN B, 1993, MAKROMOL CHEM-RAPID, V14, P799

[4]

CORAIN B, 1993, P EUROPACAT 1 MONTP, V1, P349

[5]

GIANNANDREA R, 1994, J MOL CATAL, V99, P27

[6] A CONVENIENT METHOD FOR THE PREPARATION OF ACETAL CARBOXYLIC-ACIDS BY NICKEL(II) COMPLEX-CATALYZED OXYGENATION OF ALPHA-ALKOXY CYCLIC-KETONES WITH MOLECULAR-OXYGEN [J].

HATA, E ;

TAKAI, T ;

YAMADA, T ;

MUKAIYAMA, T .

CHEMISTRY LETTERS, 1994, (03) :535-538

[7]

MARCHON JC, 1989, SYNTHESIS-STUTTGART, P389

[8] CATALYTIC ACTIVITY OF A POLYMERIZABLE TRIS(BETA-KETOESTERATE)IRON(III) COMPLEX TOWARDS THE OXIDATION OF ORGANIC SUBSTRATES [J].

MASTRORILLI, P ;

NOBILE, CF .

TETRAHEDRON LETTERS, 1994, 35 (24) :4193-4196

[9]

MASTRORILLI P, 1993, 22 C NAZ CHIM IN VIL, P415

[10]

MASTRORILLI P, 1994, J MOL CATAL, V99, P19

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