A CONVENIENT METHOD FOR THE PREPARATION OF ACETAL CARBOXYLIC-ACIDS BY NICKEL(II) COMPLEX-CATALYZED OXYGENATION OF ALPHA-ALKOXY CYCLIC-KETONES WITH MOLECULAR-OXYGEN

被引：13

作者：

HATA, E

TAKAI, T

YAMADA, T

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 03期

关键词：

D O I：

10.1246/cl.1994.535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of nickel(II) complex, various alpha-alkoxy cyclic ketones are smoothly oxygenated into acetal lactones by combined use of molecular oxygen and aldehydes at room temperature under an atmospheric pressure. Successive treatment of formed acetal lactones with hydrogen chloride in alcohols affords the corresponding acetal carboxylic acids in good to quantitative yields.

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页码：535 / 538

页数：4

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