ASYMMETRIC AEROBIC EPOXIDATION OF UNFUNCTIONALIZED OLEFINS CATALYZED BY OPTICALLY-ACTIVE ALPHA-ALKOXYCARBONYL-BETA-KETOIMINATO MANGANESE(III) COMPLEXES

被引：121

作者：

MUKAIYAMA, T ^{[1
]}

YAMADA, T ^{[1
]}

NAGATA, T ^{[1
]}

IMAGAWA, K ^{[1
]}

机构：

[1] MITSUI PETROCHEM IND CO LTD, BASIC RES LABS ORGAN SYNTH, SODEGAURA, CHIBA 29902, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 02期

关键词：

D O I：

10.1246/cl.1993.327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Optically active N, N'-ethylenebis(alpha-alkoxycarbonyl-beta-ketoimine) was found to be a new class of effective ligand of manganese(III) complex catalyst for the asymmetric aerobic epoxidation of simple olefins, such as 1,2-dihydronaphthalene derivatives, to afford the corresponding optically active epoxides with good to high enantioselectivities.

引用

页码：327 / 330

页数：4

共 19 条

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