OXYGEN INSERTION INTO PALLADIUM-ARENE BONDS BY IODOSYLBENZENE

被引：24

作者：

BHAWMICK, R ^{[1
]}

BISWAS, H ^{[1
]}

BANDYOPADHYAY, P ^{[1
]}

机构：

[1] UNIV N BENGAL,DEPT CHEM,RAJA RAMMOHANPUR 734430,W BENGAL,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 498卷 / 01期

关键词：

PALLADIUM; OXYGEN INSERTION;

D O I：

10.1016/0022-328X(95)05476-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The regiospecific hydroxylation of the naphthyl ring at the C(2) position of unsymmetrical 1-(phenylazo)naphthalene 1 was achieved via oxygen atom insertion into the palladium-naphthyl bond of 2 with iodosylbenzene, followed by demetallation: The insertion of oxygen atom into the Pd-C(phenyl) bond of the cyclopalladated azobenzenes 5 was also achieved with iodosylbenzene.

引用

页码：81 / 83

页数：3

共 26 条

[1] ASTERS PL, 1993, ORGANOMETALLICS, V12, P4691
[2] IODOSOBENZENE AND PERSULFATE OXYGENATION OF SATURATED-HYDROCARBONS CATALYZED BY DIPHOSPHINO COMPLEXES OF RUTHENIUM(III)
BRESSAN, M
FORTI, L
MORVILLO, A
[J]. INORGANICA CHIMICA ACTA, 1993, 211 (02) : 217 - 220
[3] Carbtree R. H., 1985, CHEM REV, V85, P245
[4] FORMATION OF COVALENT BONDS FROM PLATINUM OR PALLADIUM TO CARBON BY DIRECT SUBSTITUTION
COPE, AC
SIEKMAN, RW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (14) : 3272 - &
[5] Furniss B.S., 1978, VOGELS TXB PRACTICAL
[6] CYCLOMETALATION OF ARYLAZO COMPOUNDS .3. DETERMINATION OF THE CHELATE RING SIZE IN A PERI-PALLADATED 1-ARYLAZONAPHTHALENE BY N-15 NUCLEAR MAGNETIC-RESONANCE
GEHRIG, K
HUGENTOBLER, M
KLAUS, AJ
RYS, P
[J]. INORGANIC CHEMISTRY, 1982, 21 (06) : 2493 - 2494
[7] ASYMMETRIC HYDROXYLATION BY A CHIRAL IRON PORPHYRIN
GROVES, JT
VISKI, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) : 8537 - 8538
[8] GROVES JT, 1980, METAL ION ACTIVATION, P125
[9] HAYAISHI O, 1974, MOL MECHANISMS OXYGE
[10] Hill C. L., 1989, ACTIVATION FUNCTIONA

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