IODOSOBENZENE AND PERSULFATE OXYGENATION OF SATURATED-HYDROCARBONS CATALYZED BY DIPHOSPHINO COMPLEXES OF RUTHENIUM(III)

被引：10

作者：

BRESSAN, M ^{[1
]}

FORTI, L ^{[1
]}

MORVILLO, A ^{[1
]}

机构：

[1] UNIV PADUA,DIPARTIMENTO CHIM INORGAN MET ORGAN & ANALIT,I-35131 PADUA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 211卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)85605-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydroxylation and/or ketonization of alkanes (adamantane, cyclo-octene, hexane) is achieved by using iodosobenzene or aqueous mono-persulfate at room temperature in the presence of catalytic amounts of ruthenium(III)-diphosphino complexes dissolved in dichloromethane. On the basis of the kinetic behavior, different oxidizing metal species are proposed for the oxidations with mono-persulfate and with iodosobenzene.

引用

页码：217 / 220

页数：4

共 42 条

[1] SELECTIVE OXIDATION OF ALCOHOLS BY A H2O2-RUCL3 SYSTEM UNDER PHASE-TRANSFER CONDITIONS
BARAK, G
DAKKA, J
SASSON, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) : 3553 - 3555
[2] RUTHENIUM(III)-CATALYSED HYDROGEN-PEROXIDE OXIDATION OF ALKYL AROMATIC-COMPOUNDS UNDER PHASE-TRANSFER CONDITIONS
BARAK, G
SASSON, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (10) : 637 - 638
[3] MECHANISM OF THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY GIF SYSTEMS - RELATIONSHIP WITH METHANE MONOOXYGENASE
BARTON, DHR
CSUHAI, E
DOLLER, D
OZBALIK, N
BALAVOINE, G
[J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1990, 87 (09) : 3401 - 3404
[4] ALKENE EPOXIDATION BY RUTHENIUM(II) PHOSPHINE COMPLEXES - A KINETIC INVESTIGATION
BRESSAN, M
MORVILLO, A
[J]. INORGANIC CHEMISTRY, 1989, 28 (05) : 950 - 953
[5] 5-COORDINATE COMPLEXES OF RUTHENIUM(II) WITH DI(TERTIARY PHOSPHINES)
BRESSAN, M
RIGO, P
[J]. INORGANIC CHEMISTRY, 1975, 14 (09) : 2286 - 2288
[6] SELECTIVE OXYGENATION OF ALIPHATIC ETHERS CATALYZED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
ROMANELLO, G
[J]. INORGANIC CHEMISTRY, 1990, 29 (16) : 2976 - 2979
[7] SELECTIVE OXIDATION OF ALKANES AND ETHERS MEDIATED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (07) : 421 - 423
[8] RUTHENIUM-CATALYZED OXYGENATION OF SATURATED-HYDROCARBONS BY T-BUTYLHYDROPEROXIDE
BRESSAN, M
MORVILLO, A
ROMANELLO, G
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1992, 77 (03): : 283 - 288
[9] CENTI G, 1990, NEW DEV SELECTIVE OX, P119
[10] CENTI G, 1992, J MOL CATAL, V71, P149

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