COBALT(II)-FACILITATED TRANSPORT OF DIOXYGEN IN A POLYSTYRENE MEMBRANE

被引：10

作者：

BARNES, MJ ^{[1
]}

DRAGO, RS ^{[1
]}

BALKUS, KJ ^{[1
]}

机构：

[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1988年 / 110卷 / 20期

关键词：

Membranes--Permeability; Mechanical; -; Polystyrenes; Separation--Equipment;

D O I：

10.1021/ja00228a028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The authors present conclusive evidence to illustrate that reversible binding of O2 to transition-metal O2 carriers can be utilized to facilitate transport of O2 through a solid membrane when such complexes are incorporated into the membrane. The key experiment to establish this concept involves the proper selection of a blank film. The polystyrene-supported CoSDPT type complexes and blanks consisting of nickel(II) derivatives are ideal for demonstrating facilitated transport because of their structural similarity. We also present a procedure for evaluating permeation data, which should find widespread use in this area since it eliminates imperfections that can exist in test and blank membranes. A transport mechanism is discussed in light of these results.

引用

页码：6780 / 6785

页数：6

共 32 条

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