CATALYTIC-OXIDATION OF NAPHTHALENE ON PALLADIUM IN COOPERATION WITH COPPER(I) (II) REDOX COUPLE

被引：12

作者：

KURODA, Y

KUNAI, A

HAMADA, M

KITANO, T

ITO, S

SASAKI, K

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Kagamiyama, Higashi-Hiroshima

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 10期

关键词：

D O I：

10.1246/bcsj.64.3089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic oxidation of naphthalene in moist acetic acid solutions has been studied. The catalyst used was a silica-supported palladium which works in cooperation with the Cu+/Cu2+ redox couple. Products were 1-naphthol, 1,4-naphthoquinone and (E)-2-formylcinnamaldehyde with a total yield of more than 78% in which naphthoquinone shared 40%. Reaction mechanism has been discussed in comparison with that of benzene.

引用

页码：3089 / 3093

页数：5