SOLVENT-FREE [1.1.1]PROPELLANE FROM 1,3-DIIODOBICYCLO[1.1.1]PENTANE

被引：30

作者：

ALBER, F ^{[1
]}

SZEIMIES, G ^{[1
]}

机构：

[1] UNIV MUNICH,INST ORGAN CHEM,KARLSTR 23,W-8000 MUNICH 2,GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 03期

关键词：

1.1.1]PROPELLANE; IODINE; NUCLEOPHILIC ATTACK AT;

D O I：

10.1002/cber.19921250332

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[1.1.1]Propellane (1) could be prepared free of solvent by reaction of 1,3-diiodobicyclo[1.1.1]pentane (3) with sodium cyanide in dimethyl sulfoxide (DMSO). Highly pure 1 was obtained in an overall yield of more than 50% related to the propellane precursor 1,1-dibromo-2,2-bis(chloromethyl)cyclopropane (2).

引用

页码：757 / 758

页数：2

共 22 条

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