THE PHOTODISSOCIATION OF O-3 - A CLASSICAL DYNAMIC APPROACH FOR THE INTERPRETATION OF THE RECURRENCES IN THE AUTOCORRELATION FUNCTION

被引：21

作者：

FARANTOS, SC ^{[1
]}

TAYLOR, HS ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 07期

关键词：

D O I：

10.1063/1.460573

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Families of periodic orbits and the classical survival probability function are calculated for ozone in the excited 1B2 state. It is shown that some of the observed oscillations in the experimentally extracted and quantum mechanically calculated time autocorrelation functions can be explained by certain types of periodic orbits. Disagreements between the calculated and experimental correlation function are attributed to inaccuracies of the potential function used.

引用

页码：4887 / 4895

页数：9

共 48 条

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