THE EFFECT OF ADDED MOLECULAR-SIEVES ON ALKENE EPOXIDATION REACTIONS CATALYZED BY [MOO2CL2L], WHERE L IS A 3-(DIETHOXYPHOSPHORYL) DERIVATIVE OF CAMPHOR

被引：19

作者：

CLARKE, R ^{[1
]}

COLEHAMILTON, DJ ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 12期

关键词：

D O I：

10.1039/dt9930001913

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of molecular sieves to the alkene epoxidation system consisting of Bu(t)OOH and [MoO2Cl2L], where L is a 3-(diethoxyphosphoryl) derivative of camphor increases both the rate and yield of the epoxidation reactions; for styrene maximum conversions of 25% which are subsequently degraded are converted to stable conversions of 96% with 94% selectivity to styrene oxide by adding 4A molecular sieves.

引用

页码：1913 / 1914

页数：2

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