USE OF MOLECULAR-SIEVES FOR PROMOTION OF DIASTEREOSELECTIVITY IN PALLADIUM-CATALYZED OXIDATIVE CYCLIZATION - REVERSAL OF DIASTEREOFACIAL SELECTIVITY

被引：9

作者：

HEUMANN, A ^{[1
]}

TOTTIE, L ^{[1
]}

MOBERG, C ^{[1
]}

机构：

[1] ROYAL INST TECHNOL,DEPT ORGAN CHEM,S-10044 STOCKHOLM 70,SWEDEN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 04期

关键词：

D O I：

10.1039/c39910000218

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecular sieves have a decisive influence on the oxidative cyclisation of cis-1,2-divinylcyclohexane, resulting in enhanced diastereoselectivity (17-62%) as well as, occasionally, in opposite absolute configuration of the newly created chiral centres.

引用

页码：218 / 220

页数：3

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