CYCLIC SYSTEMS BY PALLADIUM-CATALYZED OXIDATION OF DIOLEFINS

被引：36

作者：

HEUMANN, A

REGLIER, M

WAEGELL, B

机构：

[1] Laboratoire de Stéréochimie, associé au CNRS, Université d' Aix-Marseille, Centre de St-Jérôme, Marseille

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Substituted bi‐ and polycyclic compounds are accessible from diolefins such as (1), (3), and 5 by reaction with PdCL2 as catalyst in the presence of CuCL2/HOAc/NaOAc. The yields of reactions (3) → (4) (77%) and (5) → (4) (40%) suggest that 3 has the “correct” stereochemistry for ring closure. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：866 / 867

页数：2

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