MECHANISTIC ASPECTS OF THE PALLADIUM-CATALYZED CYCLIZATION OF 5-METHYLENECYCLOOCTENE

被引：23

作者：

HEUMANN, A

REGLIER, M

WAEGELL, B

机构：

[1] Laboratoire de Stéréochimie associé au CNRS, Université d'Aix-Marseille, Centre de St-Jérôme, Marseille

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 11期

关键词：

D O I：

10.1002/anie.197908671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An insight into the course of the Pd‐catalyzed oxidation of diolefins is provided by reaction of 5‐methylenecyclooctene 1 with PdCl2/CuCl2/HOAc/NaOAc to give the bicyclic compounds 2 to 5. In benzene, the diolefin 1 reacts with Pd(PhCN)2Cl2 to form the isolable σ‐π complex 6 which cyclizes in hitherto unexplained manner to compounds 2 to 5. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：867 / 868

页数：2

共 12 条

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