STRONG HYDROGEN-BONDS IN ACID SELENITES - CORRELATION OF INFRARED SPECTROSCOPIC AND STRUCTURAL DATA

被引：43

作者：

UNTERDERWEIDE, K ^{[1
]}

ENGELEN, B ^{[1
]}

BOLDT, K ^{[1
]}

机构：

[1] UNIV SIEGEN,D-57068 SIEGEN,GERMANY

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1994年 / 322卷

关键词：

D O I：

10.1016/0022-2860(94)87040-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Several hitherto unknown acid selenites of divalent metals have been prepared and characterized by means of infrared spectroscopy and X-ray structure determination. The relations between the O-H...O stretching and bending vibrations and the O-H...O distances of the strongly hydrogen-bonded hydroxyl groups of these compounds and of some other acid selenites are presented. They are discussed with respect to the nature of the ABC trio-bands in the nu(OH) stretching mode region of strongly hydrogen-bonded systems.

引用

页码：233 / 239

页数：7

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