INFRARED-ABSORPTION IN HYDROGEN-BONDED COMPLEXES AND ABSORPTION OF AN EXCESS ELECTRON IN HYDROGEN-BONDED SOLVENTS

被引：7

作者：

ABRAMCZYK, H

机构：

[1] Institute of Applied Radiation Chemistry, Technical University, 93-590 Łódź

来源：

VIBRATIONAL SPECTROSCOPY | 1993年 / 5卷 / 01期

关键词：

INFRARED SPECTROMETRY; EXCESS-ELECTRONS; HYDROGEN-BONDED COMPLEXES; HYDROGEN-BONDED SOLVENTS; INFRARED ABSORPTION;

D O I：

10.1016/0924-2031(93)87060-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A comparison was made between the theories of IR absorption in hydrogen-bonded complexes and near-IR and visible absorption of an excess electron in hydrogen-bonded solvents. The near-IR and visible absorption spectra of excess electrons in water, alcohols, amines and alkanes were calculated in terms of electron-vibron coupling. The role of the hydrogen bond on electron stabilization and solvation is discussed.

引用

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页码：109 / 117

页数：9

相关论文

共 55 条

[1] ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON IN AMMONIA AND AMINES [J].

ABRAMCZYK, H ;

KROH, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) :5749-5753

[2] INTERACTION-INDUCED CONTRIBUTION TO CHANGES IN THE INFRARED-SPECTRUM OF HYDROGEN-BONDED COMPLEXES [J].

ABRAMCZYK, H .

CHEMICAL PHYSICS, 1987, 116 (02) :249-257

[3] PROFILES OF THE NU-S(X-H) MODE IN IR-SPECTRA OF HYDROGEN-BONDED COMPLEXES - THEORETICAL APPROACH [J].

ABRAMCZYK, H .

CHEMICAL PHYSICS, 1985, 94 (1-2) :91-98

[4] ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON .2. NUMERICAL-CALCULATIONS OF THE PROFILES OF THE ELECTRON IN WATER AND METHANOL AT 300-K [J].

ABRAMCZYK, H ;

KROH, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (16) :6155-6159

[5] ABSORPTION-SPECTRA OF A SOLVATED ELECTRON IN ETHERS [J].

ABRAMCZYK, H ;

KROH, J .

CHEMICAL PHYSICS, 1991, 157 (03) :373-379

[6] IR NU-S(XH) ABSORPTION-BAND SHAPE OF H-BONDED COMPLEX IN CONDENSED MEDIA .2. NUMERICAL-CALCULATIONS OF THE PROFILES [J].

ABRAMCZYK, H .

CHEMICAL PHYSICS, 1990, 144 (03) :319-326

[7] IR NU-S(XH) ABSORPTION-BAND SHAPE IN H-BONDED COMPLEX .1. THEORY [J].

ABRAMCZYK, H .

CHEMICAL PHYSICS, 1990, 144 (03) :305-318

[8] ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON .1. THEORY [J].

ABRAMCZYK, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (16) :6149-6155

[9] NEAR-IR ABSORPTION-SPECTRUM OF THE SOLVATED ELECTRON IN ALCOHOLS, DEUTERATED WATER, AND DEUTERATED GLASSES - LACK OF OBSERVANCE OF THE NEAR-IR SPECTRUM IN H2O GLASSES [J].

ABRAMCZYK, H ;

KROH, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (09) :3653-3658

[10] RELAXATION DYNAMICS FOLLOWING TRANSITION OF SOLVATED ELECTRONS [J].

BARNETT, RB ;

LANDMAN, U ;

NITZAN, A .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :4413-4422

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