FAST-ION-INDUCED FLUORESCENCE FROM J-AGGREGATE OF CYANINE DYE IN LANGMUIR-BLODGETT-FILMS

被引:2
作者
ASAI, K [1 ]
SEKI, S [1 ]
SATO, T [1 ]
ISHIGURE, K [1 ]
SHIBATA, H [1 ]
机构
[1] UNIV TOKYO,NUCL SCI & TECHNOL RES CTR,TOKAI,IBARAKI 31911,JAPAN
关键词
FLUORESCENCE; ION BOMBARDMENT; LANGMUIR-BLODGETT FILMS; RADIATION DAMAGE;
D O I
10.1016/0040-6090(95)80050-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The luminescence from pseudo-isocyanine Langmuir-Blodgett films induced by the irradiation of charged particles with energy of the order of megaelectronvolts has been measured. The damaged cross-sections for the emission yield in the cases of H+ and He+ were determined and related to an effective coherent size of J aggregate. In addition to the fluorescence from the well-known excitonic states (J band) which had been observed with photo-excitation, a new band was found at lower frequencies in emission spectra. The experimental results indicate that the mobilities of the species responsible for this band are larger than those for the J band.
引用
收藏
页码:286 / 291
页数:6
相关论文
共 29 条
[21]   Auxiliary valency as the cause of variability in the absorption spectra in solutions [J].
Scheibe, G .
ANGEWANDTE CHEMIE, 1937, 50 :0212-0219
[22]  
Scheibe G., 1936, ANGEW CHEM, V49, P563
[23]   ON THE THEORY OF VIBRONIC STRUCTURE OF LINEAR AGGREGATES - APPLICATION TO PSEUDOISOCYANIN (PIC) [J].
SCHERER, POJ ;
FISCHER, SF .
CHEMICAL PHYSICS, 1984, 86 (03) :269-283
[24]  
SCLMRDT R, 1991, PHYS REV B, V44, P560
[25]  
SMITH DL, 1974, PHOTOGR SCI ENG, V18, P309
[26]   SUPERRADIANCE IN MOLECULAR AGGREGATES [J].
SPANO, FC ;
MUKAMEL, S .
JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (02) :683-700
[27]   TEMPERATURE-DEPENDENT SUPERRADIANT DECAY OF EXCITONS IN SMALL AGGREGATES [J].
SPANO, FC ;
KUKLINSKI, JR ;
MUKAMEL, S .
PHYSICAL REVIEW LETTERS, 1990, 65 (02) :211-214
[28]   ANNIHILATION OF SINGLET EXCITONS IN J-AGGREGATES OF PSEUDOISOCYANINE (PIC) STUDIED BY PICOSECOND AND SUBPICOSECOND SPECTROSCOPY [J].
SUNDSTROM, V ;
GILLBRO, T ;
GADONAS, RA ;
PISKARSKAS, A .
JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (05) :2754-2762
[29]   MECHANISM OF SPUTTERING OF LARGE BIOMOLECULES BY IMPACT OF HIGHLY IONIZING PARTICLES [J].
WILLIAMS, P ;
SUNDQVIST, B .
PHYSICAL REVIEW LETTERS, 1987, 58 (10) :1031-1034