LASER-POWERED HOMOGENEOUS PYROLYSIS OF TRIISOBUTYLGALLANE AND TRI-TERT-BUTYLGALLANE

被引：10

作者：

GRADY, AS

LINNEY, RE

MARKWELL, RD

MILLS, GP

RUSSELL, DK

WILLIAMS, PJ

JONES, AC

机构：

[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND

[2] EPICHEM LTD,WIRRAL L62 3QF,MERSEYSIDE,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1992年 / 2卷 / 05期

关键词：

TRI-TERT-BUTYLGALLANE; TRIISOBUTYLGALLANE; INFRARED LASER PYROLYSIS; PRODUCT ANALYSIS;

D O I：

10.1039/jm9920200539

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas-phase pyrolysis of tri-tert-butylgallane and triisobutylgallane has been studied using infrared laser-powered homogeneous pyrolysis. Identification of products by infrared and NMR spectroscopies confirmed that the predominant reaction pathway is beta-hydride elimination in both cases, but that the pyrolysis proceeds at a significantly lower temperature than that of triethylgallium.

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页码：539 / 543

页数：5

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