BREVIFOLIOL - A STRUCTURE REVISION

被引：14

作者：

CHU, A

ZAJICEK, J

TOWERS, GHN

SOUCYBREAU, CM

LEWIS, NG

CROTEAU, R

机构：

[1] WASHINGTON STATE UNIV,INST BIOL CHEM,467 CLARK HALL,PULLMAN,WA 99164

[2] WASHINGTON STATE UNIV,UNIV NMR SPECTROSCOPY CTR,PULLMAN,WA 99164

[3] UNIV BRITISH COLUMBIA,DEPT BOT,VANCOUVER V6T 2B1,BC,CANADA

[4] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER V6T 2B1,BC,CANADA

来源：

PHYTOCHEMISTRY | 1993年 / 34卷 / 01期

关键词：

TAXUS-BREVIFOLIA; TAXACEAE; TAXANES; BREVIFOLIOL;

D O I：

10.1016/S0031-9422(00)90817-3

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Brevifoliol is an abundant metabolite found in the needles of the Pacific yew (Taxus brevifolia). Its structure has been revised such that the acetate and benzoate functionalities originally considered to be attached to C-10 and C-7, respectively, are transposed, i.e. brevifoliol is 10beta-benzoxy-7beta,9alpha-diacetoxy-1beta,5alpha,13alpha-trihydroxy-taxa-4(20),11-diene.

引用

页码：269 / 271

页数：3