SYNTHESIS AND MOLECULAR-STRUCTURES OF NOVEL 7-COORDINATED OXO-RHENIUM(V) AND NITRIDO-RHENIUM(V) COMPLEXES OF 2,2'/6',2''/6'',2'''-QUATERPYRIDINE

被引：28

作者：

CHE, CM ^{[1
]}

WANG, YP ^{[1
]}

YEUNG, KS ^{[1
]}

WONG, KY ^{[1
]}

PENG, SM ^{[1
]}

机构：

[1] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 18期

关键词：

D O I：

10.1039/dt9920002675

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [ReO2(PPh3)2I] and [ReNCl2(PPh3)2] with 2,2': 6',2": 6",2"'-quaterpyridine (L) in methanol gave [ReO(L)(OMe)2]ClO4 and [ReN(L)(PPh3)Cl]ClO4 respectively. The structures determined by X-ray crystallography revealed seven-co-ordination around rhenium with Re=O and Re=N distances of 1.666(4) and 1.647(6) angstrom respectively. Intense metal-to-ligand charge-transfer transitions in the visible region and reversible Re(VI)-Re(V) redox couples have been observed for both complexes in acetonitrile.

引用

页码：2675 / 2677

页数：3

共 14 条

[1] METAL-NITRIDO PHOTO-OXIDANTS - SYNTHESIS, PHOTOPHYSICS, AND PHOTOCHEMISTRY OF [OSVI(NH3)4(N)] (X)3 (X = CL, CF3SO3)
CHE, CM
LAU, TC
LAM, HW
POON, CK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (02) : 114 - 116
[2] METAL NITRIDO AND IMIDO PHOTO-OXIDANTS - PHOTOPHYSICS AND PHOTOCHEMISTRY OF NITRIDO AND IMIDO COMPLEXES OF OSMIUM(VI) AND X-RAY CRYSTAL-STRUCTURE OF [PH4AS]2[OSVI(CN)5N]
CHE, CM
LAM, MHW
MAK, TCW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) : 1529 - 1531
[3] RHENIUM(V) OXIDE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF THE COMPOUNDS TRANS-ETEI2O(OET)(PPH3)2,TRANS-MEEI2O(OME)(PPH3)2 AND OF THEIR HYDROLYSIS DERIVATIVE REIO2(PPH3)2
CIANI, GF
DALFONSO, G
ROMITI, PF
SIRONI, A
FRENI, M
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1983, 72 (01): : 29 - 37
[4] OXYGEN ATOM TRANSFER-REACTIONS OF CATIONIC RHENIUM(III), RHENIUM(V), AND RHENIUM(VII) TRIAZACYCLONONANE COMPLEXES
CONRY, RR
MAYER, JM
[J]. INORGANIC CHEMISTRY, 1990, 29 (24) : 4862 - 4867
[5] A CONVENIENT PREPARATION OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE AND BIS(ACETONITRILE)-(2,2'-6',2''-6'',2'''-QUATERPYRIDINE)NICKEL(II) HEXAFLUOROPHOSPHATE ACETONITRILE(1/1)
CONSTABLE, EC
ELDER, SM
HEALY, J
TOCHER, DA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05): : 1669 - 1674
[6] STUDIES OF METAL-NITROGEN MULTIPLE BONDS .2. CRYSTAL AND MOLECULAR STRUCTURE OF NITRIDODICHLOROBIS(TRIPHENYLPHOSPHINE)RHENIUM(V) RENCL2(P(C6H5)3)2
DOEDENS, RJ
IBERS, JA
[J]. INORGANIC CHEMISTRY, 1967, 6 (02) : 204 - &
[7] METAL-CENTERED OXYGEN ATOM TRANSFER-REACTIONS
HOLM, RH
[J]. CHEMICAL REVIEWS, 1987, 87 (06) : 1401 - 1449
[8] STUDIES OF RHENIUM-OXYGEN BOND .4. REINVESTIGATION OF "DIOXOBIS(ETHYLENEDIAMINE)RHENIUM(V) CHLORIDE AND DIOXOTETRAKIS(PYRIDINE)RHENIUM(V) CHLORIDE DIHYDRATE
LOCK, CJL
TURNER, G
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAR): : 923 - 927
[9] CRYSTAL-STRUCTURE OF AQUA(2,2'=6',2'' =6'',2'''-QUATERPYRIDYL)SULPHITOCOBALT-(III) NITRATE MONOHYDRATE
MASLEN, EN
RASTON, CL
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (04): : 323 - 326
[10] PHOTOPHYSICS AND PHOTOCHEMISTRY OF RHENIUM(V)-NITROGEN TRIPLE BONDS
NEYHART, GA
BAKIR, M
BOAZ, J
VINING, WJ
SULLIVAN, BP
[J]. COORDINATION CHEMISTRY REVIEWS, 1991, 111 : 27 - 32

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