Neutron Diffraction Study of the ZnFe2-xCrxO4 Series

被引:27
作者
Oles, A. [1 ]
机构
[1] Inst Nucl Tech, Krakow, Poland
来源
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE | 1970年 / 3卷 / 03期
关键词
D O I
10.1002/pssa.19700030303
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZnFe2-xCrO4 spinels with x = 0, 0.1, 0.5, 1.0, 1.5, 1.9, and 2.0 were investigated. The lattice and the oxygen parameter were determined by means of X-ray and of neutron diffraction methods, The neutron diffraction pattern at T = 4.2 degrees K for a compound with x = 0.1 is similar to those of ZnFe2O4. For 0.5 <= x < 1.5 short-range magnetic order is observed at low temperatures. A detailed analysis of the magnetic structure of the compound with x = 1.9 is performed. The magnetic unit cell is 2 a, 2 a, 2 a and the spin arrangement as for MgCr2O4. The Neel temperature is T-N = 16 degrees K and the magnetic moment of the Cr3+ ion is equal to 2.4 mu(B).
引用
收藏
页码:569 / 577
页数:9
相关论文
共 18 条
[12]  
PLUMIER R, 1967, C R ACAD SCI FRANCE, V264, P672
[13]  
PLUMIER R, 1968, THESIS
[14]   MOSSBAUER STUDY OF NORMAL FERRITES WITH SPINEL STRUCTURE [J].
SAWICKI, J .
CZECHOSLOVAK JOURNAL OF PHYSICS, 1967, 17 (04) :371-&
[15]  
SHIRANE S, 1964, J APPL PHYS, V35, P954
[16]  
TAKEI WJ, 1963, PHYS REV, V129, P2009
[17]   PHYSICAL PROPERTIES AND CATION ARRANGEMENT OF OXIDES WITH SPINEL STRUCTURES .1. CATION ARRANGEMENT IN SPINELS [J].
VERWEY, EJW ;
HEILMANN, EL .
JOURNAL OF CHEMICAL PHYSICS, 1947, 15 (04) :174-180
[18]  
1963, AMERICAN INSTITUTE O, P5