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PORPHYRINS COUPLED WITH NUCLEOSIDE BASES - SYNTHESIS AND CHARACTERIZATION OF ETHER-LINKED ADENINE-THYMINE AND GUANINE-CYTOSINE DERIVATIVES
被引:13
作者:
HISATOME, M
IKEDA, K
KISHIBATA, S
YAMAKAWA, K
机构:
来源:
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D O I:
10.1246/cl.1993.1357
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Porphyrins having an adenine-thymine or guanine-cytosine pair have been synthesized. Spectroscopic study has revealed that the two nucleobases form inter- and intramolecular base pairs in anti and syn atropisomers, respectively, and that the guanine-cytosine pair is more close to the porphyrin ring than the adenine-thymine pair.
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页码:1357 / 1360
页数:4
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