[(C6H5)(4)P](1)(INFINITY)[CU3I4] - THE FIRST COMPOUND WITH A HELICAL CHAIN OF FACE-SHARING TETRAHEDRA AS A STRUCTURAL ELEMENT

被引：41

作者：

HARTL, H

MAHDJOURHASSANABADI, F

机构：

[1] Institut Für Anorganische Und Analytische Chemie Der Freien Universität, Berlin, D-14195

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1002/anie.199418411

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Face‐sharing tetrahedra arranged in a helix (idealized form shown below) mark the structure of the iodocuprate 1, which was obtained from Ph4PI, I2, and Cu. Five Cu positions were identified at room temperature; at lower temperatures only three (slow cooling) or four (rapid cooling) are occupied. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1841 / 1842

页数：2

共 18 条

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ANDERSSON, S
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MAHDJOURHASSANABADI, F
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[8] SYNTHESIS AND STRUCTURAL INVESTIGATION OF IODOCUPRATES(I) .7. [(CO(CP)2)(CUI23)]3, [(CO(CP)2)(CUI2)]4, COBALTOCENIUM IODOCUPRATES(I) WITH UNUSUAL ANION STRUCTURES
HARTL, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (09): : 927 - 928
[9] HARTL H, 1984, Z NATURFORSCH B, V39, P149
[10] HARTL H, 1981, ANGEW CHEM INT EDIT, V30, P772

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