[(C6H5)(4)P](1)(INFINITY)[CU3I4] - THE FIRST COMPOUND WITH A HELICAL CHAIN OF FACE-SHARING TETRAHEDRA AS A STRUCTURAL ELEMENT

被引:41
作者
HARTL, H
MAHDJOURHASSANABADI, F
机构
[1] Institut Für Anorganische Und Analytische Chemie Der Freien Universität, Berlin, D-14195
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 18期
关键词
D O I
10.1002/anie.199418411
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Face‐sharing tetrahedra arranged in a helix (idealized form shown below) mark the structure of the iodocuprate 1, which was obtained from Ph4PI, I2, and Cu. Five Cu positions were identified at room temperature; at lower temperatures only three (slow cooling) or four (rapid cooling) are occupied. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:1841 / 1842
页数:2
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