SINTERING OF POWDERS OF POLYAROMATIC MESOPHASE TO HIGH-STRENGTH ISOTROPIC CARBONS .1. INFLUENCE OF THE RAW-MATERIAL AND SINTERING CONDITIONS ON THE PROPERTIES OF THE CARBON MATERIALS

被引：53

作者：

HOFFMANN, WR

HUTTINGER, KJ

机构：

[1] Institut für Chemische Technik der Universität Karlsruhe, 76128 Karlsruhe

来源：

CARBON | 1994年 / 32卷 / 06期

关键词：

MESOPHASE; PARTICLE SIZE; SINTERING; HIGH-TEMPERATURE TREATMENT; FINE-GRAINED CARBONS;

D O I：

10.1016/0008-6223(94)90218-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The sintering of compacted mesophase powders of varying nature and particle size was studied. The sintered carbons were stepwise heat-treated to 2600-degrees-C, and their properties were determined after each step. The sintering process is composed of a transient liquid-phase sintering step and a subsequent reaction sintering step in the solid state. The investigation of both process steps and the properties of the heat-treated carbons indicate that the initial transient liquid-phase sintering is the decisive step, and thus predetermines the properties of the heat-treated carbons. After graphitization treatment of sintered carbons at 2400-degrees-C, flexural strength values up to 160 MPa were obtained. Criteria for the selection of the mesophase, the particle size, and the sintering conditions are discussed.

引用

页码：1087 / 1103

页数：17

共 50 条

[1] [Anonymous], 1945, J PHYS
[2] BEHRENBECK K, 1987, THESIS U KARLSRUHE
[3] BEHRENBECK K, 1989, 19TH BIENN C CARB ST, P174
[4] BEHRENKBECK, 1987, THESIS U KARSLRUHE
[5] BRIGGS DKH, 1964, FUEL, V43, P439
[6] CRISTU N, 1964, BER DEUT KERAM GES, V41, P143
[7] ANALYSIS OF COHERENCE, STRAIN, THERMAL VIBRATION AND PREFERRED ORIENTATION IN CARBONS BY X-RAY-DIFFRACTION
ERGUN, S
[J]. CARBON, 1976, 14 (03) : 139 - 150
[8] EXNER E, 1978, MATERIALKUNDLICH T 4
[9] FITZER E, 1977, HIGH TEMP HIGH PRESS, V9, P243
[10] FITZER E, 1987, 18TH BIENN C CARB WO, P40

← 1 2 3 4 5 →