ASYMMETRIC ADDITION OF DIETHYLZINC TO AROMATIC-ALDEHYDES USING ENANTIOMERICALLY PURE HYDROXYMETHYL OXAZOLINE LIGANDS

被引：26

作者：

ALLEN, JV ^{[1
]}

FROST, CG ^{[1
]}

WILLIAMS, JMJ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 04期

关键词：

D O I：

10.1016/S0957-4166(00)80170-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of diethylzinc to aromatic aldehydes in the presence of catalytic amounts of enantiomerically pure hydroxymethyl oxazolines affords the corresponding secondary alcohols with modest levels of asymmetric induction.

引用

页码：649 / 650

页数：2

共 16 条

[1] BALAVOINE G, 1989, TETRAHEDRON LETT, V30, P514
[2] ASYMMETRIC CATALYSIS .44. ENANTIOSELECTIVE MONOPHENYLATION OF DIOLS WITH CU(OAC)2/PYRIDINYLOXAZOLINE CATALYSTS
BRUNNER, H
OBERMANN, U
WIMMER, P
[J]. ORGANOMETALLICS, 1989, 8 (03) : 821 - 826
[3] DESIGNED CATALYST FOR ENANTIOSELECTIVE DIELS-ALDER ADDITION FROM A C2-SYMMETRICAL CHIRAL BIS(OXAZOLINE)-FE(III) COMPLEX
COREY, EJ
IMAI, N
ZHANG, HY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) : 728 - 729
[4] HIGHLY ENANTIOSELECTIVE CATALYTIC DIELS-ALDER ADDITION PROMOTED BY A CHIRAL BIS(OXAZOLINE)-MAGNESIUM COMPLEX
COREY, EJ
ISHIHARA, K
[J]. TETRAHEDRON LETTERS, 1992, 33 (45) : 6807 - 6810
[5] BIS(OXAZOLINES) AS CHIRAL LIGANDS IN METAL-CATALYZED ASYMMETRIC REACTIONS - CATALYTIC, ASYMMETRIC CYCLOPROPANATION OF OLEFINS
EVANS, DA
WOERPEL, KA
HINMAN, MM
FAUL, MM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) : 726 - 728
[6] FROST CG, 1992, TETRAHEDRON, V48, P2143
[7] HELMCHEN G, 1991, SYNLETT, P257
[8] ENANTIOSELECTIVE CONJUGATE ADDITION OF GRIGNARD-REAGENTS TO ENONES CATALYZED BY CHIRAL ZINC(II) COMPLEXES
JANSEN, JFGA
FERINGA, BL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (13) : 4168 - 4175
[9] ASYMMETRIC CATALYTIC CYCLOPROPANATION OF OLEFINS - BIS-OXAZOLINE COPPER-COMPLEXES
LOWENTHAL, RE
ABIKO, A
MASAMUNE, S
[J]. TETRAHEDRON LETTERS, 1990, 31 (42) : 6005 - 6008
[10] ASYMMETRIC SYNTHESIS OF R AND S ALPHA-ALKYLALKANOIC ACIDS FROM METALATION AND ALKYLATION OF CHIRAL 2-OXAZOLINES
MEYERS, AI
KNAUS, G
KAMATA, K
FORD, ME
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (02) : 567 - 576

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