STUDIES ON SAMARIUM DIIODIDE INITIATED ADDITION-REACTION OF FLUOROALKYL IODIDES TO ALKYNES AND ITS MECHANISM

被引:37
作者
MA, SM [1 ]
LU, XY [1 ]
机构
[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0040-4020(01)85421-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Samarium diiodide was found to be an effective initiator in the addition reaction of fluoroalkyl iodides to alkynes. A single electrontransfer radical chain mechanism was proposed for the reaction based on ESR studies and other experimental results. © 1990.
引用
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页码:357 / 364
页数:8
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