STUDIES ON SAMARIUM DIIODIDE INITIATED ADDITION-REACTION OF FLUOROALKYL IODIDES TO ALKYNES AND ITS MECHANISM

被引：37

作者：

MA, SM ^{[1
]}

LU, XY ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

TETRAHEDRON | 1990年 / 46卷 / 02期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0040-4020(01)85421-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Samarium diiodide was found to be an effective initiator in the addition reaction of fluoroalkyl iodides to alkynes. A single electrontransfer radical chain mechanism was proposed for the reaction based on ESR studies and other experimental results. © 1990.

引用

页码：357 / 364

页数：8

共 15 条

[11] NEW EFFICIENT PALLADIUM-CATALYZED PERFLUOROALKYLATION OF CARBON-CARBON MULTIPLE BONDS WITH F-ALKYL IODIDES - AN EXPEDIENT ROUTE TO F-ALKYLATED ALKYL AND ALKENYL IODIDES
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (10) : 2350 - 2352
[14] ADDITION OF FREE RADICALS TO UNSATURATED SYSTEMS .8. THE DIRECTION OF RADICAL-ADDITION TO ALKYL-ACETYLENES AND PERFLUOROALKYL-ACETYLENES
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[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1954, (MAY): : 1634 - 1638
[15] SAMARIUM DIIODIDE INITIATED ADDITION-REACTION OF FLUOROALKYL IODIDES TO OLEFINS
LU, XY
MA, SM
ZHU, JY
[J]. TETRAHEDRON LETTERS, 1988, 29 (40) : 5129 - 5130

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