EVIDENCE FOR A CAGE EFFECT IN THE UV PHOTOLYSIS OF HBR IN AR-HBR - THEORETICAL AND EXPERIMENTAL RESULTS

被引：62

作者：

SEGALL, J

WEN, Y

SINGER, R

WITTIG, C

GARCIAVELA, A

GERBER, RB

机构：

[1] HEBREW UNIV JERUSALEM,DEPT PHYS CHEM,IL-91904 JERUSALEM,ISRAEL

[2] HEBREW UNIV JERUSALEM,FRITZ HABER RES CTR MOLEC DYNAM,IL-91904 JERUSALEM,ISRAEL

[3] UNIV CALIF IRVINE,DEPT CHEM,IRVINE,CA 92717

[4] CSIC,INST MATEMAT & FIS FUNDAMENTAL,E-28006 MADRID,SPAIN

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 207卷 / 4-6期

关键词：

D O I：

10.1016/0009-2614(93)89037-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence for a cage effect in the 193 nm photodissociation of HBr in the Ar-HBr cluster is found. This effect manifests itself as a tail extending toward lower energies in the hydrogen photofragment kinetic energy distribution (KED). This is a consequence of energy transfer in collisions between the light and the heavy atoms. There is good agreement between the experimental and theoretical KEDs.

引用

页码：504 / 509

页数：6

共 26 条

[1] SOLVATION EFFECTS ON CHEMICAL-REACTION DYNAMICS IN CLUSTERS - PHOTODISSOCIATION OF HI IN XENHI [J].