THE PARTIAL OXIDATION OF ETHANE TO ACETALDEHYDE

被引：31

作者：

OTSUKA, K ^{[1
]}

URAGAMI, Y ^{[1
]}

HATANO, M ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,MEGURO KU,TOKYO 152,JAPAN

来源：

CATALYSIS TODAY | 1992年 / 13卷 / 04期

关键词：

D O I：

10.1016/0920-5861(92)80107-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The mixed oxide (B-P-O) prepared from H3BO3 and P2O5 was modified to a selective catalyst (B-P-O(S)) to the formation of CH3CHO after prolonged treatment in a gas mixture of reactants. The contribution of gas-phase chain reactions to the catalytic oxidations of C2H6 on the B-P-O(S) could be neglected. The catalytic active species on the B-P-O(S) was suggested to be a highly dispersed boron oxide supported on BPO4 crystals. The mixed oxide prepared from BPO4, H3BO3(7atom%), and P2O5(3atom%) showed the highest yield of CH3CHO.

引用

页码：667 / 672

页数：6

共 6 条

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[6]

OTSUKA K, 1991, NATURAL GAS CONVERSI, P15

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