DECAMETHYLALUMINOCENIUM, A PI-STABILIZED R(2)AL+ CATION

被引：95

作者：

DOHMEIER, C

SCHNOCKEL, H

ROBL, C

SCHNEIDER, U

AHLRICHS, R

机构：

[1] UNIV KARLSRUHE,INST PHYS CHEM & ELEKTROCHEM,LEHRSTUHL THEORET CHEM,D-76128 KARLSRUHE,GERMANY

[2] UNIV MUNICH,INST ANORGAN CHEM,D-80333 MUNICH,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316551

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first sandwich complex of an element from the third main group, the cation in 1, has been synthesized and characterized by spectroscopy and X‐ray crystallography (see picture). This cation is stabilized by π interactions, and the Cp* ligands are staggered. (Formula Presented.) (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

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页码：1655 / 1657

页数：3

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