SYNTHESIS OF BIOLOGICALLY-ACTIVE DRIMANES FROM (-)-SCLAREOL

被引：31

作者：

BARRERO, AF

ALVAREZMANZANEDA, E

ALTAREJOS, J

SALIDO, S

RAMOS, JM

机构：

[1] Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Granada

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 18期

关键词：

SCLAREOL; DRIMANE; OSMIUM TETROXIDE; OZONOLYSIS;

D O I：

10.1016/S0040-4039(00)76667-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enantiospecific synthesis of drimenyl acetate (8), a key intermediate in the synthesis of biologically active drimanes, and albicanyl acetate (14), potent fish antifeedant, from sclareol (1), are described. Also a short and efficient synthesis of polygodial (22), from albicanyl acetate (14), is shown.

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页码：2945 / 2948

页数：4

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