AIR OXIDATION OF A MANGANESE(III) THIOETHER CHELATE AFFORDS THE FIRST MANGANESE(III) DIHYDROSALEN COMPLEX WITH A PENDANT SULFOXIDE LIGAND

被引:5
作者
BERKESSEL, A [1 ]
BOLTE, M [1 ]
SCHWENKREIS, T [1 ]
机构
[1] UNIV FRANKFURT,INST ORGAN CHEM,D-60439 FRANKFURT,GERMANY
关键词
D O I
10.1039/c39950000535
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aerobic oxidation of the manganese(iii) dihydrosalen-thioether chelate rac-1 affords the novel manganese(HI) sulfoxide complex rac-2; X-ray structural analysis of the latter reveals that only one of the two possible diastereomeric oxidation products is present in the crystal.
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页码:535 / 536
页数:2
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