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REACTIVITY OF GAMMA-SUBSTITUTED BETA-FUNCTIONAL ALLYL ORGANOZINC COMPOUNDS - PREPARATION OF BETA-SUBSTITUTED AND GAMMA-SUBSTITUTED ALPHA-METHYLENE-GAMMA-BUTYROLACTONES

被引：21
作者：
LAMBERT, F
KIRSCHLEGER, B
VILLIERAS, J
机构：
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 406卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(91)83172-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Stable organozinc compounds derived from alkyl 3-alkyl 2-(bromomethyl) propenoates reacted with ketones and aldehydes to give alpha-methylene gamma-butyrolactones in excellent yields. Different reaction parameters were studied and some transition states were proposed.
引用
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页码：71 / 86
页数：16
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