EFFECTS OF TH DOPING ON STRUCTURAL AND SUPERCONDUCTIVE PROPERTIES OF LA2-XBAXCUO4

The striking suppression of superconductivity of La2-xBaxCuO4 in a narrow range of x around 0.125 is known to be a consequence of a structural transition to a low-temperature tetragonal phase below about 60 K. Study of low-temperature lattice instabilities by x-ray diffraction revealed that in La2-y-xThyBaxCuO4 the development of the low-temperature tetragonal phase, as well as the sharp suppression of superconductivity, is centered at x-y congruent-to 0.125, instead of x congruent-to 0.125. Therefore, the anomalous low-temperature behavior is essentially characterized by the density of carriers rather than local ionic forces, which couples with the lattice instabilities.