A GENERAL-METHOD OF PROMOTING OXIDATIVE ADDITION OF C-H BONDS TO IRIDIUM(I) USING AZINE PHOSPHINES

被引：12

作者：

PERERA, SD ^{[1
]}

SHAW, BL ^{[1
]}

机构：

[1] UNIV LEEDS,SCH CHEM,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 10期

关键词：

D O I：

10.1039/c39940001203

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of [IrCl(CO)(2)(p-toluidine)] with azine phosphines of type Z,E-Ph(2)CH(2)C(Bu(t))=N-N=C(Q)R, Q = H or Me, R = an organic group, activates aryl, heterocyclic, alkenyl or aliphatic C-H bonds to give cyclometallated iridium(III) hydrides.

引用

页码：1203 / 1204

页数：2

共 12 条

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