DYNAMICS OF INTRAMOLECULAR CARBENIC REARRANGEMENTS

被引：23

作者：

MOSS, RA

机构：

[1] Department of Chemistry, Rutgers, The State University of New Jersey, New Brunswick

来源：

PURE AND APPLIED CHEMISTRY | 1995年 / 67卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1351/pac199567050741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report deals with several topics of current interest in mechanistic carbene chemistry, including the absolute kinetics of carbenic rearrangements; substituent effects on 1,2-shifts; entropic control in carbenic rearrangements; the involvement of electronically excited diazirines as carbene mimics; and the magnitude of kinetic isotope effects, particularly in 1,2-H(D) migrations.

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收藏

页码：741 / 747

页数：7

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