Wannier type impurity states in naphthalene-rare gas matrices and the energy of the quasi-free electron state

被引:5
作者
Angus, J. G. [1 ]
Morris, G. C. [1 ]
机构
[1] Univ Queensland, Dept Chem, St Lucia, Qld 4067, Australia
关键词
D O I
10.1016/0009-2614(70)85113-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Absorption and photoemission spectra of naphthalene-rare gas matrices are reported. Bands arising from transitions to the n = 2, 3 impurity Wannier states of naphthalene in this condensed system are observed. From measured values of the molecular ionization potential. threshold energy for electron photoemission and ionization potential of the naphthalene in the matrix. values of the medium polarization energy by the positive hole and the energy of the quasi-free excess electron in the medium are deduced.
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页码:480 / 482
页数:3
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