DESYMMETRIZATION OF MESO PROPARGYLIC DIOLS

被引：18

作者：

ADJE, N ^{[1
]}

BREUILLES, P ^{[1
]}

UGUEN, D ^{[1
]}

机构：

[1] IND CHIM STRASBOURG,ECOLE EUROPEENNE HAUTES ETUDES,SYNTH ORGAN LAB,CNRS,1 RUE BLAISE PASCAL,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)60642-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Meso acetylenic diols, conveniently separated from their threo isomers via the corresponding adducts with bromine, have been converted into optically pure derivatives by either lipase-catalysed hydrolysis of the corresponding diacetates or ketalisation of (+) - menthone.

引用

页码：4631 / 4634

页数：4

共 14 条

[1] TOWARDS THE SYNTHESIS OF PRISTINAMYCIN PIIA - PREPARATION OF THE OPTICALLY PURE C-3/C-7 FRAGMENT
ADJE, N
BREUILLES, P
UGUEN, D
[J]. TETRAHEDRON LETTERS, 1992, 33 (16) : 2151 - 2154
[2] BACKVALL JE, 1985, J AM CHEM SOC, V107, P6892
[3] BREUILLES P, IN PRESS
[4] Dupont G, 1909, CR HEBD ACAD SCI, V149, P1381
[5] DUPONT G, 1912, THESIS PARIS
[6] GENERATION AND USE OF A ZINC DERIVATIVE OF A FUNCTIONALIZED 1,3-OXAZOLE - SOLUTION OF THE VIRGINIAMYCIN MADUMYCIN OXAZOLE PROBLEM
GANGLOFF, AR
AKERMARK, B
HELQUIST, P
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (18) : 4797 - 4799
[7] ENANTIOSELECTIVE HYDROLYSES BY BAKERS-YEAST .3. MICROBIAL RESOLUTION OF ALKYNYL ESTERS USING LYOPHILIZED YEAST
GLANZER, BI
FABER, K
GRIENGL, H
[J]. TETRAHEDRON, 1987, 43 (24) : 5791 - 5796
[8] LETT R, 1972, B SOC CHIM FR, P2299
[9] PREPARATION OF MONOLITHIUM ACETYLIDE IN TETRAHYDROFURAN - REACTION WITH ALDEHYDES AND KETONES
MIDLAND, MM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (15) : 2250 - 2252
[10] PREPARATIVE BIO-ORGANIC CHEMISTRY .1. SYNTHESIS OF OPTICALLY-ACTIVE ALKYNYL ALCOHOLS AND ALPHA-HYDROXY ESTERS BY MICROBIAL ASYMMETRIC HYDROLYSIS OF THE CORRESPONDING ACETATES
MORI, K
AKAO, H
[J]. TETRAHEDRON, 1980, 36 (01) : 91 - 96

← 1 2 →