MAGNETIC DOUBLE RESONANCE STUDIES OF PENTAFLUOROPHENYL DERIVATES

被引：21

作者：

DEAN, RR

MCFARLAN.W

机构：

[1] Division of Molecular Science, National Physical Laboratory, Teddington, Middlesex

[2] Department of Chemistry, Sir John Cass College

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 05期

关键词：

D O I：

10.1039/j29690000509

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homo- and hetero-nuclear double resonance experiments are used to facilitate the complete analysis of the n.m.r. spectra of C6F 5Z (Z = CHO, CH3, and CF3). An accurate relation is presented between the 19F and 1H resonant frequencies in C6F6 and tetramethylsilane respectively. A novel decoupling method is described for the measurement of very small coupling constants, and is applied to C6F5 · CH3.

引用

页码：509 / &

共 15 条

[1] FLUORINE-19 NUCLEAR MAGNETIC RESONANCE STUDIES ON SOME POLYFLUROAROMATIC COMPOUNDS AND THEIR METAL COMPLEXES
BRUCE, MI
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (07): : 1459 - &
[2] PHASE-LOCK CIRCUIT FOR A 100 MHZ NUCLEAR MAGNETIC RESONANCE SPECTROMETER
CHARLES, A
[J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1968, 1 (01): : 64 - &
[3] ADAPTATION OF A HIGH RESOLUTION NUCLEAR MAGNETIC RESONANCE SPECTROMETER FOR HETERONUCLEAR DOUBLE RESONANCE EXPERIMENTS
CHARLES, A
MCFARLANE, W
[J]. MOLECULAR PHYSICS, 1968, 14 (03) : 299 - +
[4] HETERONUCLEAR DOUBLE RESONANCE STUDY OF PENTAFLUOROBENZENE
DEAN, RR
MCFARLANE, W
[J]. MOLECULAR PHYSICS, 1968, 15 (03) : 321 - +
[5] NUCLEAR MAGNETIC DOUBLE RESONANCE WITH AN INCOHERENT RADIO-FREQUENCY FIELD
ERNST, RR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (10) : 3845 - &
[6] DETECTION OF VERY SMALL NMR SPIN COUPLING CONSTANTS BY RESOLUTION ENHANCEMENT
ERNST, RR
FREEMAN, R
GESTBLOM, B
LUSEBRINK, TR
[J]. MOLECULAR PHYSICS, 1967, 13 (03) : 283 - +
[7] FLUORINE NUCLEAR MAGNETIC RESONANCE SPECTRA OF SOME POLYFLUOROAROMATIC COMPOUNDS
FIELDS, R
LEE, J
MOWTHORPE, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1968, (03): : 308 - +
[8] GUTOWSKY HS, 1959, J CHEM PHYS, V30, P717
[9] HIGH-RESOLUTION FLUORINE MAGNETIC RESONANCE SPECTRA OF SOME PENTAFLUOROPHENYL DERIVATIVES
LAWRENSO.IJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1965, (FEB): : 1117 - +
[10] HIGH-RESOLUTION FLUORINE MAGNETIC RESONANCE SPECTRA OF PENTAFLUOROANISOLE
LAWRENSON, IJ
JONES, RG
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1967, (08): : 797 - +

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