SYNTHESIS AND CHARACTERIZATION OF NEW HEMIPORPHYRAZINATO NICKEL-COMPLEXES

被引:9
作者
HABERROTH, K [1 ]
RACK, M [1 ]
RUFF, D [1 ]
HANACK, M [1 ]
机构
[1] UNIV TUBINGEN,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY
关键词
HEMIPORPHYRAZINES; HEMINAPHTHOPORPHYRAZINES; NICKEL COMPLEXES;
D O I
10.1002/cber.19951280414
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new substituted (hemiporphyrazinato)nickel complexes [HpNi] 3-9 and 11-14, the (heminaphthoporphyrazinato)nickel complexes 15-19 [HnpNi], and the hemianthracenophorphyrazine complex [HapNi] 20 are prepared from isoindolenines la-e and 10a-d, diaminopyridines 2a-e and nickel acetate. The compounds were characterized by H-1- and C-13-NMR spectroscopy. The H-1-NMR spectrum of the mixture of the 3,18/3,19-substituted (C-2v/C-Zh) complexes is discussed.
引用
收藏
页码:417 / 421
页数:5
相关论文
共 24 条
[21]  
SOMMERAUER M, THESIS U TUBINGEN
[22]  
SPIESSENS LI, 1988, B SOC CHIM BELG, V97, P431
[23]   INFRARED AND NUCLEAR MAGNETIC RESONANCE STUDIES OF SOME TIN PHTHALOCYANINES AND HEMIPORPHYRAZINES [J].
SUTTON, LE ;
KENNEY, ME .
INORGANIC CHEMISTRY, 1967, 6 (10) :1869-&
[24]  
TEDESCHI RE, 1967, Patent No. 3329569