Easy access to C,C'-bifunctionalized 1H-phosphirene-tungsten complexes: Evidence for ambiphilic reaction behaviour of a phosphanediyl-tungsten complex

被引：24

作者：

Ostrowski, A ^{[1
]}

Jeske, J ^{[1
]}

Jones, PG ^{[1
]}

Streubel, R ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期

关键词：

D O I：

10.1039/C39950002507

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 2H-azaphosphirene-tungsten complex 1 reacts with ethoxyacetylene 2a or dimethyl acetylenedicarboxylate 2b to yield C,C'-bifunctionalized 1H-phosphirene-tungsten complexes 4a,b; compounds 4a,b are characterized by NMR spectroscopy (C-13, P-31) and complex 4a by single-crystal X-ray diffraction.

引用

页码：2507 / 2508

页数：2

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