[(MEN(CH2CH2NME2)2LI)2CL][HC(SIME2N(4-CH3C6H4))3SN], A SOLVENT-SEPARATED TRIPODAL TRIS(AMIDO)STANNATE AND A [LI2CL]+ CATION REVISITED

被引：28

作者：

HELLMANN, KW ^{[1
]}

STEINERT, P ^{[1
]}

GADE, LH ^{[1
]}

机构：

[1] UNIV WURZBURG,INST ANORGAN CHEM,AM HUBLAND,D-97074 WURZBURG,GERMANY

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 18期

关键词：

D O I：

10.1021/ic00096a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and a single-crystal X-ray structure analysis of the tripodal (amido)-stannate [{MeN(CH2CH2NMe2)2Li}2Cl][HC{SiMe2N(4-CH3C6H4)}3Sn] (3) are reported. The lithium stannate crystallizes as a solvent-separated ion pair with an exposed Sn atom as part of a [2.2.2]bicyclooctane-derived cage structure. The counterion contains a bent [Li2Cl]+ unit [angle Li-Cl-Li' = 143.1(6)-degrees].

引用

页码：3859 / 3860

页数：2

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