SYNTHESIS OF A NEW CLASS OF ASYMMETRIC KETONE REDUCTION CATALYST VIA A DIASTEREOSELECTIVE CYCLIZATION REACTION - X-RAY CRYSTAL-STRUCTURE OF S(P)R-(-)-N-(TERT-BUTYLDIPHENYLSILYL)DIHYDROBENZAZAPHOSPHOLE OXIDE

被引:16
作者
BURNS, B
MERIFIELD, E
MAHON, MF
MOLLOY, KC
WILLS, M
机构
[1] UNIV BATH,SCH CHEM,CLAVERTON DOWN,BATH BA2 7AY,AVON,ENGLAND
[2] UNIV BATH,SCH CHEM,XRAY CRYSTALLOG UNIT,BATH BA2 7AY,AVON,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 19期
关键词
D O I
10.1039/p19930002243
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A stereoselective synthesis and X-ray crystal structure of dihydrobenzazaphosphole oxide S(P)R-trans-8, a precursor of a new class of asymmetric ketone reduction catalyst, is described.
引用
收藏
页码:2243 / 2246
页数:4
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